PPPoE Connection Setup - Windows XP

Click Start, then click Control Panel.

Click Network Connections & Internet Connections.

Click on Network Connections.

Click Create a new Connection.

Select Connect to the Internet and then next.

Select Set up my Connection manually.

Select Connect using a broadband connection that requires a user name and password.

ISP Name: iPrimus Fibre.

Username: username@dsl2.iprimus.com.au

Password: user specific 

Then click next

Then tick add shortcut ,Then click Finish , and Click connect on desktop shortcut.